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PCN-224(H)

PCN-224(H)

【Numbering】BK2021013013 【CAS】1476810-88-4
【Item No.】 【specification】
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Material name: PCN-224(H)
Other name: NA
CAS: 1476810-88-4
Structure information
Unit molecular formula C144H72N12O64Zr15+2 Unit molecular weight 4362.51448
Coordination metal Zr ligand Tetracarboxyphenyl porphyrin H2TCPP (CAS: 14609-54-2)
Pore diameter 1.9nm Pore volume 1.59 cm3/g
Specific surface BET specific surface 2600 m2/g

Analog structure

Product traits
Product appearance red brown powder
Reddish Brown Powder
Particle size
stability
1) Long-lasting stability in the air, stable in aqueous solution and acid-weak alkali solution (PH 0-11)
2) Thermal decomposition temperature is about >400℃
Preservation and activation methods
1) Store in a dry and airtight condition at room temperature or low temperature
2) It is recommended to activate the oven at 80 degrees (vacuum) for 12 hours before use
Other features
Fluorescence: excitation wavelength 430nm, emission wavelength 652nm, showing red light
Application field
1) PCN-224(Co) has high catalytic activity for CO2/propylene oxide coupling reaction
2) PCN-224 shows up to 8.25mmol/g adsorption capacity for C3H8 at room temperature and 100kPa
3) PCN-224 can image cells and can be used as a photosensitizer to treat tumors
4) PCN-224 can detect Hg ions and nitro compounds, and PCN-224 (Pt) can detect oxygen.
 
Characterization map
references
1) D. Feng, W.-C. Chung, Z. Wei, Z.-Y. Gu, H.-L. Jiang, Y.-P. Chen, DJ Darensbourg, and H.-C. Zhou, J . Am. Chem. Soc. 2013, 135, 17105-17110, DOI: 10.1021/ja408084j
2) J. Park, Q. Jiang, D. Feng, L. Mao, and H.-C. Zhou, J. Am. Chem. Soc. 2016, 138, 3518-3525, DOI: 10.1021/jacs.6b00007


Warm tips: Suzhou Beike nano products are only used for scientific research, not for human body,different batches of products have different specifications and performance

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Warm tips: Suzhou Beike nano products are only used for scientific research, not for human body,different batches of products have different specifications and performance.The website pictures are from the Internet. The pictures are for reference only. Please take the real object as the standard. In case of infringement, please contact us to delete them immediately.
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